A cyclic process can be represented very clearly in the ts diagram. The pressureenthalpy diagram or p h diagram is a tool that all hvac and refrigeration engineers should be able to use proficiently. Based on thermodynamic properties of hfc4a 2 tetra. Ph diagram is to analysis the feasibility of the refrigeration cycle, to calculate the thermodynamic properties of the refrigeration system. It has been in use since the early 1990s and now, in 2019, we are beginning to see its popularity wane with the rise of the new hfo refrigerant known as r1234yf. The pressureenthalpy diagram log p h diagram is a very useful tool for refrigerant technicians. How can i plot the ph diagram for my system using ees. Similarly, the expansion device is characterized by the suction and discharge pressures.
Coolpack was developed by the department of mechanical engineering mek, section of thermal energy tes at the technical university of denmark dtu. Ts diagram of stirling cycles a and ericsson cycles b. The content and the intellectual layout in this chart are property of nrf bv. The areas between the curves define the limits of temperature and pressure at which different phases can exist. Po box, the heath, runcorn, cheshire, wa7 4qx tele. This diagram describes the relationship of pressure and enthalpy of a select refrigerant.
Enthalpy kjkg 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 440 460 480 500 520 540 560 pressure bar 0,50 0,60 0,70 0,80 0,90 1,00. Plotting of p h and ts diagrams of fluoropropylenes. Temperature is slightly harder to read than other properties. Case1 the basics of refrigeration cycle ph diagram analysis. New tables of the thermodynamic properties of hfc4a have been. Refrigerants such as r4a have been developed and are now included in the.
The design is to be based upon the ideal vaporcompression refrigeration cycle, with four components. The vapor is compressed, following the constant entropy line to. R4a pressure enthalpy chart the engineering mindset. With thermodynamic properties that are very similar to those of r4a, isobutane was used in germany as early as 1992 to replace r12. Thermodynamic properties saturation table 1415 contents. A pressure enthalpy graph is individual for each refrigerant. Explanations of ph diagram refrigerant characteristics table. This page can be removed for errorreporting, feedback, other units etc. Pressureenthalpy chart, r4a 1,1,1,2tetrafluoroethane. Based on the program allprops, center for applied thermodynamic studies, university of idaho. By knowing the zone divided with saturation curve in which the intersection point of pressure.
The comparison is based on coefficient of performance cop obtained by the refrigerant in the refrigeration cycle, and various cycle parameters. The saturated vapor entering the compressor suction would be at 20. Pdf plotting of ph and ts diagrams of fluoropropylenes. The ph diagram is a graphical representation of the refrigerant as it travels through the refrigeration system. Mclinden thermophysics division national institute of standards and technology. The vapor is compressed, following the constant entropy line to the pressure cor.
That being said, there are still millions of cars on the road that. The ph diagram of the refrigeration cycle with all the operating conditions are as the following. Isobaric, isochoric and supercritical thermal energy storage in r4a. Enthalpy kjkg 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 440 460 480 500 520 540 560 pressure bar 0. An isotherm, or equal temperature line, has a downward slope until is hits the liquidvapor dome. The performance of the heat pump cycle using the binary refrigerant mixture r4a r123 was. Fundamentals of refrigeration li 001 v3 fundamentals of refrigeration. R4a refrigerant pressure temperature chart refrigerant hq. Figuring out the vapor fraction in a ln ph diagram. Modified rankine cycle on p v diagram for steam engines. Thermodynamic properties of hfc4a reading advantage 3 pdf refrigerant. Pdf the report addresses issues of plotting the pressureenthalpy and temperatureentropy. This case is also to evaluate various cycles such as with penalties, economizing for a. In the log ph diagram the pressure p is plotted above the p.
Danfoss light commercial refrigeration compressors b, u, l, p, x, s ranges 60hz. The characteristics of temperature gradients for pressure and enthalpy are shown on p h diagrams, called isothermal lines. Plotting of ph and ts diagrams of fluoropropylenes. R4a is the most common refrigerant found in automobiles today. This dependency can be seen on the pressureenthalpy diagram.
The pressureenthalpy ph diagram is a useful tool for refrigeration engineers and designers. Danfoss light commercial refrigeration compressors frcc. May 25, 2019 r4a is the most common refrigerant found in automobiles today. Pressure enthalpy diagram melting line40 o 40 c2 02 0. The ct, et and tr are the same as practice1 except the liquid is subcooled to 20. It is an ebook for people who are involved in training and. First, an explanation of how the diagram is built up is given, and then its use is describ ed. The compressor does work on the refrigeration system consumes energy. Fluoropropylenes, pressureenthalpy diagram, temperatureentropy diagram. Properties of refrigerant r22 saturated liquid and saturated vapor both imperial.
In order to properly understand this diagram, it is best to go through the vapor compression cycle on a p h diagram. How can i plot the ph diagram for my system using ees software. The input and output format was aloo changed to yield. The points on these curves indicate the pressure and corresponding temperatures under which two different phases can exist in equilibrium e. Figuring out the vapor fraction in a ln p h diagram.
Pressure enthalpy diagram melting line40 o 40 c2 02 0 t 0 o c 0 0 20 40 40 60 60 80 80 100 100 120 120 140 140 160 160 180 180 200 200 220 220. Huber national institute of standards and technology, marcia. Thermodynamics enthalpy entropy mollier and steam tables i. Figure a15 nelsonobert generalized compressibility chart. Use the ph diagram analysis, all the refrigerant flow rates and operating conditions at the design point for the system can be clearly determined.
Isobaric, isochoric and supercritical thermal energy storage in r4a benjamin i. Download a pdf copy of the pressure enthalpy chart for both metric and imperial units. This definition of enthalpy can be expressed, mathematically, as follows. H figure 14 ph diagram for basic refrigeration circuit the expansion device is between points 4 and 1. Sherpha project transcritical r744 heat pumps technicians manual 862 1. Welcome to the manual for refrigeration servicing technicians. Light commercial refrigeration compressors b, u, l, p, x.
Bookmark this page email this page download this page as pdf print this page facebook. Positively innovative r32 instructions for use and handling refrigerants r32. Entropy is the measure of the amount of disorder in the system. Thermodynamic properties of r4a 1,1,1,2tetrafluoroethane. Like the pn diagram, there are regions on a ph diagram in which two phases exist together. The pressureenthalpy diagram or ph diagram is a tool that all hvac and refrigeration engineers should be able to use proficiently. Appendix b log ph diagrams for refrigerants experts in brazed plate heat exchangers swep is a worldleading supplier of brazed plate heat exchangers for hvac and industrial applications. Conditioning and refrigeration relations, tables and charts. The performance of the heat pump cycle using the binary refrigerant mixture r4ar123 was. For single refrigerants such as r22 and r4a, the isot hermal line has no gradient in the saturated area, that is, the saturation temperature under certain pressure is the same at both the liquid side and the gas side. Positively innovative refrigerants r32 daikin chemical europe.
Since this is a ln pressureenthalpy graph, the enthalpy is marked on the xaxis. Cops of r718 in comparision with other modern refrigerants a. Once the line hits the liquidvapor dome, the isotherm has no slope and is horizontal. Manual for refrigeration servicing introduction technicians.
An r4a refrigeration system condenses at 95 f and evaporates at 45 f. A ph diagram can be constructed for any pure substance. Thermodynamic properties of rl34a l,1,1,2tetrafluoroethane 1 marcia l. More displacement, more efficient, compactness range. Evaluation of hfo1234yf as a potential replacement for r4a in refrigeration. In the past the most popular fluids have been ammonia r717,fluorocarbons and halo carbons. Refrigeration cycle refrigeration is the transfer of heat from a lower temperature region to a higher temperature region refrigeration cycle is the vaporcompression refrigeration cycle, where the refrigerant is vaporized and condenses alternately and is compressed in the vapor phase. Modified rankine cycle on pv diagram for steam engines. Thermodynamic properties of r4a 1,1,1,2tetrafluoroethane m. The pressureenthalpy diagram log ph diagram is a very useful tool for refrigerant technicians. Isobutane r600a isobutane is a hydrocarbon, and hence is flammable. A suitable range of the mollier chart has been selected for actual.
An overview of cptes in r4a is given by the ht diagram in figure 2. In order to properly understand this diagram, it is best to go through the vapor compression. A pressure enthalpy ph diagram exhibits the same features as a pn diagram. The refrigerant flow diagram is to be read in conjunction with the p h diagram to get the entire picture of the system. R22 properties of r22 vapor volume, enthalpy and entropy at pressures.
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